I haven't seen this chain characterization in the textbooks I've used, but it's trivial to prove using a known result from infinitary order theory. (A poset is chain-complete iff it is directed-complete.) Surely, this has been done before. I just don't know where.
Rather than develop a bunch of order theory I didn't have time for in my topology class, I typed up an "elementary" proof, using "just" a well-ordering, that chain compactness is equivalent to the compactness in the usual sense.
If you know a thing or two about posets, you will recognize that the proof trivially generalizes into a proof that posets are chain-complete if and only if directed-complete. I don't know if my proof approach is new. But my recollection is that the standard proof uses induction on cardinality of the chains and directed sets, which I think is conceptually more elaborate than my approach of using a well-ordering to extract a minimal bad chain from a bad directed set.
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